Pozzuoli to Vicenza trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Pozzuoli Solfatara and arrive at Vicenza every about 2 hours on average. If travelling with Trenitalia, you need to know the Pozzuoli to Vicenza train schedule: the first train leaves at 06:23, while the last ride is at 14:53. A Pozzuoli to Vicenza train cost about 101.45 €. But how long is the train ride from Pozzuoli to Vicenza? Your journey takes about 7 hours on average.