Rosolini to Alessandria trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Rosolini and arrive at Alessandria every about 3 hours on average. If travelling with Trenitalia, you need to know the Rosolini to Alessandria train schedule: the first train leaves at 09:11, while the last ride is at 20:24. A Rosolini to Alessandria train cost about 125.95 €. But how long is the train ride from Rosolini to Alessandria? Your journey takes about 21 hours on average.