Sassuolo to Castelvetrano trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Rubiera and arrive at Castelvetrano every about 6 hours on average. If travelling with Trenitalia, you need to know the Sassuolo to Castelvetrano train schedule: the first train leaves at 17:23, while the last ride is at 17:32. A Sassuolo to Castelvetrano train cost about 215.45 €. But how long is the train ride from Sassuolo to Castelvetrano? Your journey takes about 20 hours on average.