Sciacca to Alessandria trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Castelvetrano and arrive at Alessandria every about 6 hours on average. If travelling with Trenitalia, you need to know the Sciacca to Alessandria train schedule: the first train leaves at 07:01, while the last ride is at 10:52. A Sciacca to Alessandria train cost about 132.15 €. But how long is the train ride from Sciacca to Alessandria? Your journey takes about 15 hours on average.