Sienna to Licata trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Siena and arrive at Licata every about 6 hours on average. If travelling with Trenitalia, you need to know the Sienna to Licata train schedule: the first train leaves at 17:43, while the last ride is at 18:43. A Sienna to Licata train cost about 115.8 €. But how long is the train ride from Sienna to Licata? Your journey takes about 21 hours on average.