Syracuse to Sciacca trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Siracusa and arrive at Castelvetrano every about 12 hours on average. If travelling with Trenitalia, you need to know the Syracuse to Sciacca train schedule: the first train leaves at 13:00, while the last ride is at 13:00. A Syracuse to Sciacca train cost about 19.1 €. But how long is the train ride from Syracuse to Sciacca? Your journey takes about 9 hours on average.