Tivoli to Catanzaro trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Tivoli and arrive at Catanzaro every about 2 hours on average. If travelling with Trenitalia, you need to know the Tivoli to Catanzaro train schedule: the first train leaves at 07:59, while the last ride is at 21:37. A Tivoli to Catanzaro train cost about 55.3 €. But how long is the train ride from Tivoli to Catanzaro? Your journey takes about 9 hours on average.