Tivoli to Pozzallo trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Tivoli and arrive at Pozzallo every about 12 hours on average. If travelling with Trenitalia, you need to know the Tivoli to Pozzallo train schedule: the first train leaves at 20:20, while the last ride is at 20:20. A Tivoli to Pozzallo train cost about 223.15 €. But how long is the train ride from Tivoli to Pozzallo? Your journey takes about 15 hours on average.