Tivoli to Syracuse trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Tivoli and arrive at Siracusa every about 3 hours on average. If travelling with Trenitalia, you need to know the Tivoli to Syracuse train schedule: the first train leaves at 05:40, while the last ride is at 20:20. A Tivoli to Syracuse train cost about 77.1 €. But how long is the train ride from Tivoli to Syracuse? Your journey takes about 13 hours on average.