Vicenza to Agrigento trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Vicenza and arrive at Agrigento Centrale every about 3 hours on average. If travelling with Trenitalia, you need to know the Vicenza to Agrigento train schedule: the first train leaves at 18:05, while the last ride is at 23:02. A Vicenza to Agrigento train cost about 114.25 €. But how long is the train ride from Vicenza to Agrigento? Your journey takes about 17 hours on average.