Vicenza to Catania trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Vicenza and arrive at Catania Centrale every about 6 hours on average. If travelling with Trenitalia, you need to know the Vicenza to Catania train schedule: the first train leaves at 18:26, while the last ride is at 18:26. A Vicenza to Catania train cost about 205.5 €. But how long is the train ride from Vicenza to Catania? Your journey takes about 14 hours on average. Thanks to Trenitalia, offers, you can save on your trip from Vicenza to Catania and find low cost tickets starting from 79 €!