Vicenza to Pozzallo trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Vicenza and arrive at Pozzallo every about 2 hours on average. If travelling with Trenitalia, you need to know the Vicenza to Pozzallo train schedule: the first train leaves at 17:08, while the last ride is at 23:02. A Vicenza to Pozzallo train cost about 120.15 €. But how long is the train ride from Vicenza to Pozzallo? Your journey takes about 17 hours on average.