Catania to Milan trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Catania Acquicella and arrive at Milano Centrale every about 12 hours on average. If travelling with Trenitalia, you need to know the Catania to Milan train schedule: the first train leaves at 08:04, while the last ride is at 08:04. A Catania to Milan train cost about 150.0 €. But how long is the train ride from Catania to Milan? Your journey takes about 13 hours on average. Thanks to Trenitalia, offers, you can save on your trip from Catania to Milan and find low cost tickets starting from 39 €!