To get from Livorno a Misterbianco by train you can catch one of the 5 trains that everyday travel between Livorno Centrale and Catania Acquicella, the closest station to the city. For your trip from Livorno Centrale to Catania Acquicella by train you can choose to leave from one of Livorno Centrale main stations: Livorno Centrale If travelling with Trenitalia, you need to know the Livorno Centrale to Catania Acquicella train schedule: the first train leaves at 06:03, while the last ride is at 19:29. A Livorno Centrale to Catania Acquicella train cost about 95.4 €. But how long is the train ride from Livorno Centrale to Catania Acquicella? Your journey takes about 15 hours on average.