Livorno to Pozzallo trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Livorno Centrale and arrive at Pozzallo every about 6 hours on average. If travelling with Trenitalia, you need to know the Livorno to Pozzallo train schedule: the first train leaves at 17:29, while the last ride is at 18:12. A Livorno to Pozzallo train cost about 185.25 €. But how long is the train ride from Livorno to Pozzallo? Your journey takes about 17 hours on average.