Milan to Piombino trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Milano Porta Venezia and arrive at Piombino every about 12 hours on average. If travelling with Trenitalia, you need to know the Milan to Piombino train schedule: the first train leaves at 20:39, while the last ride is at 20:39. A Milan to Piombino train cost about 50.6 €. But how long is the train ride from Milan to Piombino? Your journey takes about 9 hours on average. Thanks to Trenitalia, offers, you can save on your trip from Milan to Piombino and find low cost tickets starting from 13 €!