Modica to Livorno trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Modica and arrive at Livorno Centrale every about 3 hours on average. If travelling with Trenitalia, you need to know the Modica to Livorno train schedule: the first train leaves at 08:21, while the last ride is at 19:25. A Modica to Livorno train cost about 85.05 €. But how long is the train ride from Modica to Livorno? Your journey takes about 18 hours on average.