Syracuse to Pompei trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Siracusa and arrive at Pompei every about 4 hours on average. If travelling with Trenitalia, you need to know the Syracuse to Pompei train schedule: the first train leaves at 21:45, while the last ride is at 21:45. A Syracuse to Pompei train cost about 79.6 €. But how long is the train ride from Syracuse to Pompei? Your journey takes about 10 hours on average.