Vicenza to Arezzo trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Vicenza and arrive at Arezzo every 60 minutes on average. If travelling with Trenitalia, you need to know the Vicenza to Arezzo train schedule: the first train leaves at 05:08, while the last ride is at 23:02. A Vicenza to Arezzo train cost about 33.05 €. But how long is the train ride from Vicenza to Arezzo? Your journey takes about 4 hours on average. Thanks to Trenitalia, offers, you can save on your trip from Vicenza to Arezzo and find low cost tickets starting from 40 €!