Vicenza to Pompei trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Vicenza and arrive at Pompei every about 1 hour on average. If travelling with Trenitalia, you need to know the Vicenza to Pompei train schedule: the first train leaves at 10:02, while the last ride is at 23:02. A Vicenza to Pompei train cost about 79.85 €. But how long is the train ride from Vicenza to Pompei? Your journey takes about 9 hours on average. Thanks to Trenitalia, offers, you can save on your trip from Vicenza to Pompei and find low cost tickets starting from 36 €!