Arezzo to Alessandria trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Arezzo and arrive at Alessandria every 60 minutes on average. If travelling with Trenitalia, you need to know the Arezzo to Alessandria train schedule: the first train leaves at 06:32, while the last ride is at 22:28. A Arezzo to Alessandria train cost about 32.2 €. But how long is the train ride from Arezzo to Alessandria? Your journey takes about 7 hours on average.