Arezzo to Avola trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Arezzo and arrive at Avola every about 4 hours on average. If travelling with Trenitalia, you need to know the Arezzo to Avola train schedule: the first train leaves at 04:25, while the last ride is at 04:25. A Arezzo to Avola train cost about 130.35 €. But how long is the train ride from Arezzo to Avola? Your journey takes about 15 hours on average.