Arezzo to Palermo trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Arezzo and arrive at Palermo Notarbartolo every about 3 hours on average. If travelling with Trenitalia, you need to know the Arezzo to Palermo train schedule: the first train leaves at 18:13, while the last ride is at 22:53. A Arezzo to Palermo train cost about 92.95 €. But how long is the train ride from Arezzo to Palermo? Your journey takes about 19 hours on average. Thanks to Trenitalia, offers, you can save on your trip from Arezzo to Palermo and find low cost tickets starting from 25 €!