Arezzo to San Cataldo trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Arezzo and arrive at S. Cataldo every about 3 hours on average. If travelling with Trenitalia, you need to know the Arezzo to San Cataldo train schedule: the first train leaves at 07:25, while the last ride is at 18:13. A Arezzo to San Cataldo train cost about 111.05 €. But how long is the train ride from Arezzo to San Cataldo? Your journey takes about 12 hours on average.