Castelvetrano to Vicenza trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Castelvetrano and arrive at Vicenza every about 2 hours on average. If travelling with Trenitalia, you need to know the Castelvetrano to Vicenza train schedule: the first train leaves at 07:01, while the last ride is at 17:09. A Castelvetrano to Vicenza train cost about 122.3 €. But how long is the train ride from Castelvetrano to Vicenza? Your journey takes about 14 hours on average.