Florence to Pozzallo trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Firenze S. M. Novella and arrive at Pozzallo every about 2 hours on average. If travelling with Trenitalia, you need to know the Florence to Pozzallo train schedule: the first train leaves at 17:09, while the last ride is at 21:57. A Florence to Pozzallo train cost about 95.15 €. But how long is the train ride from Florence to Pozzallo? Your journey takes about 19 hours on average.