Grosseto to Pozzallo trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Grosseto and arrive at Pozzallo every about 2 hours on average. If travelling with Trenitalia, you need to know the Grosseto to Pozzallo train schedule: the first train leaves at 17:30, while the last ride is at 20:29. A Grosseto to Pozzallo train cost about 113.3 €. But how long is the train ride from Grosseto to Pozzallo? Your journey takes about 18 hours on average.