Livorno to Avola trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Livorno Centrale and arrive at Avola every about 2 hours on average. If travelling with Trenitalia, you need to know the Livorno to Avola train schedule: the first train leaves at 00:18, while the last ride is at 19:29. A Livorno to Avola train cost about 107.05 €. But how long is the train ride from Livorno to Avola? Your journey takes about 17 hours on average.