Livorno to Mazara del Vallo trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Livorno Centrale and arrive at Mazara del Vallo every about 6 hours on average. If travelling with Trenitalia, you need to know the Livorno to Mazara del Vallo train schedule: the first train leaves at 00:18, while the last ride is at 19:29. A Livorno to Mazara del Vallo train cost about 87.5 €. But how long is the train ride from Livorno to Mazara del Vallo? Your journey takes about 21 hours on average.