Livorno to Niscemi trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Livorno Centrale and arrive at Niscemi every about 4 hours on average. If travelling with Trenitalia, you need to know the Livorno to Niscemi train schedule: the first train leaves at 02:40, while the last ride is at 19:29. A Livorno to Niscemi train cost about 104.65 €. But how long is the train ride from Livorno to Niscemi? Your journey takes about 19 hours on average.