Matera to Pozzallo trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Reggio di Calabria Centrale and arrive at Pozzallo every about 12 hours on average. If travelling with Trenitalia, you need to know the Matera to Pozzallo train schedule: the first train leaves at 13:19, while the last ride is at 13:19. A Matera to Pozzallo train cost about 29.45 €. But how long is the train ride from Matera to Pozzallo? Your journey takes about 7 hours on average.