Naples to Vibo Valentia trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Napoli Centrale and arrive at Vibo Valentia-Pizzo every 60 minutes on average. If travelling with Trenitalia, you need to know the Naples to Vibo Valentia train schedule: the first train leaves at 12:55, while the last ride is at 23:53. Trenitalia offers 4 direct trains between these two cities. Thanks to Trenitalia, offers, you can save on your trip from Naples to Vibo Valentia and find low cost tickets starting from 12 €! When booking your train ticket a few weeks in advance though, you can find low cost trains from Naples to Vibo Valentia with fares starting from 10.90€, saving up to 26%.