Naples to Vicenza trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Napoli Centrale and arrive at Vicenza every 60 minutes on average. If travelling with Trenitalia, you need to know the Naples to Vicenza train schedule: the first train leaves at 06:10, while the last ride is at 21:32. A Naples to Vicenza train cost about 88.3 €. But how long is the train ride from Naples to Vicenza? Your journey takes about 6 hours on average. Thanks to Trenitalia, offers, you can save on your trip from Naples to Vicenza and find low cost tickets starting from 54 €!