Palermo to Mazara del Vallo trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Palermo Notarbartolo and arrive at Mazara del Vallo every about 2 hours on average. If travelling with Trenitalia, you need to know the Palermo to Mazara del Vallo train schedule: the first train leaves at 06:52, while the last ride is at 18:24. A Palermo to Mazara del Vallo train cost about 8.3 €. But how long is the train ride from Palermo to Mazara del Vallo? Your journey takes about 3 hours on average. Trenitalia offers 3 direct trains between these two cities.