Piombino to Alpignano trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Piombino and arrive at Alpignano every about 3 hours on average. If travelling with Trenitalia, you need to know the Piombino to Alpignano train schedule: the first train leaves at 06:43, while the last ride is at 15:36. A Piombino to Alpignano train cost about 50.15 €. But how long is the train ride from Piombino to Alpignano? Your journey takes about 8 hours on average.