Piombino to Ancona trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Piombino and arrive at Ancona every about 2 hours on average. If travelling with Trenitalia, you need to know the Piombino to Ancona train schedule: the first train leaves at 06:43, while the last ride is at 17:35. A Piombino to Ancona train cost about 33.9 €. But how long is the train ride from Piombino to Ancona? Your journey takes about 7 hours on average.