Piombino to Caltagirone trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Piombino and arrive at Caltagirone every about 12 hours on average. If travelling with Trenitalia, you need to know the Piombino to Caltagirone train schedule: the first train leaves at 18:56, while the last ride is at 18:56. A Piombino to Caltagirone train cost about 217.9 €. But how long is the train ride from Piombino to Caltagirone? Your journey takes about 20 hours on average.