Piombino to Niscemi trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Piombino and arrive at Niscemi every about 4 hours on average. If travelling with Trenitalia, you need to know the Piombino to Niscemi train schedule: the first train leaves at 18:20, while the last ride is at 18:56. A Piombino to Niscemi train cost about 114.9 €. But how long is the train ride from Piombino to Niscemi? Your journey takes about 16 hours on average.