Piombino to Vasto trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Piombino and arrive at Porto di Vasto every about 12 hours on average. If travelling with Trenitalia, you need to know the Piombino to Vasto train schedule: the first train leaves at 11:04, while the last ride is at 11:04. A Piombino to Vasto train cost about 75.4 €. But how long is the train ride from Piombino to Vasto? Your journey takes about 11 hours on average.