Pompei to Agrigento trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Pompei and arrive at Agrigento Bassa every about 12 hours on average. If travelling with Trenitalia, you need to know the Pompei to Agrigento train schedule: the first train leaves at 08:06, while the last ride is at 08:06. A Pompei to Agrigento train cost about 67.9 €. But how long is the train ride from Pompei to Agrigento? Your journey takes about 13 hours on average.