Pompei to Rosolini trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Pompei and arrive at Rosolini every about 12 hours on average. If travelling with Trenitalia, you need to know the Pompei to Rosolini train schedule: the first train leaves at 21:31, while the last ride is at 21:31. A Pompei to Rosolini train cost about 71.55 €. But how long is the train ride from Pompei to Rosolini? Your journey takes about 13 hours on average.