Tivoli to Sciacca trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Tivoli and arrive at Castelvetrano every about 6 hours on average. If travelling with Trenitalia, you need to know the Tivoli to Sciacca train schedule: the first train leaves at 18:35, while the last ride is at 20:18. A Tivoli to Sciacca train cost about 108.05 €. But how long is the train ride from Tivoli to Sciacca? Your journey takes about 18 hours on average.