Caltanissetta to Livorno trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Caltanissetta Centrale and arrive at Livorno Centrale every about 4 hours on average. If travelling with Trenitalia, you need to know the Caltanissetta to Livorno train schedule: the first train leaves at 10:39, while the last ride is at 17:43. A Caltanissetta to Livorno train cost about 77.0 €. But how long is the train ride from Caltanissetta to Livorno? Your journey takes about 19 hours on average.