Catanzaro to Alessandria trains might be a good value for money solution: travelling in Italy by train is often rather cheap and faster than taking a bus indeed Trains leave from Catanzaro and arrive at Alessandria every about 2 hours on average. If travelling with Trenitalia, you need to know the Catanzaro to Alessandria train schedule: the first train leaves at 06:38, while the last ride is at 14:53. A Catanzaro to Alessandria train cost about 100.5 €. But how long is the train ride from Catanzaro to Alessandria? Your journey takes about 14 hours on average.